Cien Granz (シエン・グランツ, Shien Gurantsu) is an Arrancar and a clone of the Octava (8th) Espada Szayelaporro Granz, made before the latter excised Yylfordt Granz from himself. He initially holds the rank of Arrancar Cien (100), but becomes the Cero (0) Espada after regaining his full power. After being defeated by Roka Paramia, Cien is reincarnated as a little girl who trains with Ashido Kanō to become stronger and one day fight Kenpachi Zaraki again. Cien shares many of the same characteristics as his original template, Szayelaporro. He displays a condescending attitude towards others, mocking the researchers at the Shinigami Research and Development Institute when they mistake him for the real Szayelaporro, and later ridiculing Szayelaporro himself for his defeat at the hands of Mayuri Kurotsuchi. Despite his arrogance, Cien does offer a certain level of acknowledgment, albeit sarcastically, praising the SRDI researchers for surviving an explosion caused by Kenpachi Zaraki. He is not above recognizing his limitations, as he is aware that he is not yet strong enough to challenge Zaraki and takes steps to avoid him. Cien also shares Szayelaporro's scientific mindset, originally intending to kill the SRDI researchers to experiment on them later. Cien is notably cruel, often treating both Roka Paramia and the Pícaro as disposable tools. He regards the Pícaro as nothing more than a source of sustenance and shows no hesitation in draining their energy to sustain himself. He is also enraged by the idea of being kept alive by Roka, whom he considers inferior to himself, and is shocked when she turns against him to protect Don Kanonji. Cien's quick temper is evident when he angrily grabs a Pícaro, wondering if it, too, will betray him as Roka did. Furthermore, Cien demonstrates a barbaric nature, unsuccessfully attempting to crush Zaraki's organs with Teatro de Titere and declaring to Roka that he would destroy everyone.

Giselle Gewelle (ジゼル・ジュエル, Jizeru Jueru) is a Quincy and a former member of the Wandenreich's Sternritter with the designation Z: The Zombie. Giselle Gewelle is a cheerful, playful, and seemingly carefree individual. She usually wears a happy or goofy expression, even during intense battles. She enjoys teasing and provoking others, particularly Candice Catnipp, often making fun of her temper and abilities. Despite her teasing nature, she is sometimes willing to help her companions when asked. However, beneath her cheerful appearance, Giselle has a cruel, manipulative, and unpredictable personality. She often pretends to be harmless and defenseless to make opponents underestimate her, allowing her to activate her Schrift, The Zombie. She then uses her abilities to turn defeated enemies into loyal undead servants under her control. She remains disturbingly calm while carrying out her plans and shows little concern for the suffering of others. Her cruelty can also extend to her own companions. She transformed Bambietta Basterbine into a zombie against her wishes and later did the same to several members of the Bambies, with Liltotto Lamperd being the exception. Giselle enjoys having control over her zombies and can become demanding and harsh when they disobey her. Despite her questionable treatment of others, Giselle has a complicated attachment to her companions. She occasionally shows affection toward them, helps restore their injuries, and expresses concern for their well-being in her own unusual way. Her relationship with Bambietta is particularly complicated, combining possessiveness, affection, and a strong desire to keep her close. Although Giselle often acts confident and playful, she can become frightened when her own safety is threatened. She also dislikes being insulted or underestimated and can react aggressively when someone challenges her identity or appearance. Initially, Giselle was loyal to Yhwach and wanted to earn his approval.

Lilynette Gingerbuck (リリネット・ジンジャーバック, Ririnetto Jinjābakku) is an Arrancar and Coyote Starrk's only Fracción. She is also part of the same Hollow entity as Starrk, and the two reunite into one being when he activates his Resurrección. Lilynette is cheerful, mischievous, and energetic. She enjoys bothering Starrk and finding unusual ways to wake him up. Despite her playful and childish behavior, she has a serious side. She is concerned about unusual events in Hueco Mundo and shows sadness when fellow Arrancar Aaroniero Arruruerie is defeated. She is also rather proud and dislikes being underestimated because of her small appearance. Her relationship with Starrk is unusual compared to those between other Espada and their Fracción. Rather than treating him formally or addressing him with honorifics, she simply calls him by his name. Their dynamic is more like that of siblings than a master and subordinate. Nevertheless, Lilynette respects Starrk and understands how powerful he truly is, even when he acts humble or shows little motivation. She sometimes becomes frustrated with Starrk's laid-back attitude, particularly when he allows others to take the lead despite possessing greater strength and authority. Unlike Starrk, who often lacks motivation, Lilynette is independent, determined, and energetic when they are in separate forms.

Fried (フリード, Furīdo; German for "Protection") is the Doll of Ryō Utagawa. Fried is vicious, sadistic, and remorseless like Ryō Utagawa himself; per the latter, the two are of one mind and body. She is largely loyal to Utagawa and is happy to follow his commands, but is quick to anger and will not always listen to him when enraged. Additionally, Fried considers herself a realist where Utagawa is an idealist regarding the behavior of others, and is not above threatening to stop lending her power to Utagawa if he shows any sign of weakness or is injured in battle.

Suì-Fēng (砕蜂ソイフォン, Soifon; Viz "Soi Fon"),[note 1] born Shāolíng Fēng (蜂フォン 梢綾シャオリン, Fon Shaorin; Viz "Shaolin Fon"), is the commander-in-chief of the Onmitsukidō and the captain of the Second Division in the Gotei 13. Her lieutenant is Marechiyo Ōmaeda. Suì-Fēng is fiercely loyal, disciplined, and unwavering in her beliefs. She is hardworking and has a strong sense of duty, placing great importance on following orders and completing missions. Generally reserved and serious, she is not arrogant like her lieutenant, Ōmaeda. However, she occasionally mocks her opponents or smirks during battle. She will not hesitate to confront even her own subordinates if they interfere with her duties. She tends to leave them to handle their own problems, believing that personal struggles help build character. Suì-Fēng is a member of the Shinigami Women's Association. She enjoys fish but dislikes other types of meat. Despite her strict personality, she has a softer and more personal side, particularly when it comes to her former mentor, Yoruichi Shihōin. Suì-Fēng greatly admires Yoruichi and often reminisces about their training and time together. Since Yoruichi's return, she has developed an unusual fascination with black cats, collecting cat-themed accessories, plushies, and merchandise. She even installed heated floors in the Second Division headquarters and has made several attempts to spend more time with Yoruichi. Her admiration sometimes makes her unusually shy and flustered, especially when meeting Yoruichi's younger brother, Yūshirō. As a fighter, Suì-Fēng possesses incredible determination and resolve. She is willing to make difficult decisions and endure personal hardships to accomplish her missions and defeat her enemies. She rarely displays desperation or emotion during combat, except when matters involve Yoruichi. Although she frequently criticizes Ōmaeda, she does place a certain amount of trust in him when working together.

Ellie is one of Daiji Hirasago's subordinates. Her known companions are Komae and Max. Not much is known about Ellie's personality, but she spends much of her time with her fellow companions, Komae and Max. Like the other two, Ellie appears to be very loyal to Daiji Hirasago, the Kusajishi Bull. Ellie and her companions bow respectfully before Daiji, especially when receiving orders from him.

Riruka Dokugamine (毒ヶ峰 リルカ, Dokugamine Riruka) is a Fullbringer and formerly member No. 003] of the organization known as Xcution. Confident and somewhat playful, Riruka is an impatient, hot-tempered young girl that unleashes her rage even towards her comrades if they disagree with her. She claims to be with her group only for her own agenda and not out of any loyalty to Kūgo Ginjō.] She is extremely talkative and likes having an ongoing one-sided conversation about irrelevant topics. She suffers from extreme myopia but avoids wearing glasses out of her vanity and claims contact lenses make her large eyes go dry too fast. She also has a deep seated belief in her "Survival of the Fittest" which she claimed was not truly survival of the fittest, but rather being part of the majority which dictated the predators of mankind.

She is the Plus of a deceased little girl. Ichigo Kurosaki once helped her get rid of three skateboarders who were disturbing her resting place.

Dark Rukia (ダーク ルキア, Dāku Rukia) is a Hollowfied version of Rukia Kuchiki, created when the former was forcibly merged with Homura and Shizuku through a parasitic Hollow. Being born from the siblings who erased all of Rukia's memories, Dark Rukia retains none of her former personality and instead seems to be dominated entirely from whispers of Homura and Shizuku's fused consciousness. She seeks to destroy all Shinigami, a desire spawned from the siblings' hatred of them and their wish to keep Rukia for themselves. As Homura and Shizuku’s possessive hold over her grows stronger, Dark Rukia becomes visibly more vicious and psychotic.

Dalk (ダルク, Daruku) is the Doll of Gō Koga. Dalk takes the form of an adult Human-sized creature composed entirely of metal. Her face is light gray in coloration with completely green eyes, thin red eyebrows that are constantly inwardly diagonal, a small nose, and a dark gray mouth with an equally dark tongue. The rest of her body is dark gray in coloration, with her head featuring seven triangular spikes arching outward along the edges with vertical symmetry. Her upper torso has two large breast-shaped mounds of metal on the front, multiple small bumps on the back, and a thick raised double-pointed line wrapping diagonally around the back to point downward at the front, while each of her shoulders terminates in a large metal sphere attached to the joint; each of these spheres has two arms comprised of a bone-shaped upper arm and a sharp, serrated forearm with two blades, both attached to each other and the shoulder joint by smaller metal spheres. Below the waist, Dalk has a spider-like body composed of three different sections attached to each other: the first directly below her hips is completely spherical with two legs featuring sharp tips connected to the bone-shaped thighs by small joints, the second spherical segment connected to the first has two more identical legs and an additional bean-shaped plate of metal on the underside where the legs originate from, and the third segment is more conical in shape with four spheres half-embedded in the metal at 90-degree angles. Prior to Koga and herself being empowered by Bitto serum, Dalk took on a smaller, more humanoid form where her eyes were narrow instead of circular and her head was devoid of spikes, instead being completely smooth with a small spherical protrusion on either side of her face, resembling hair.

Cquntnire Milieve (キュントナイア・ミリーヴ, Kyuntonaia Mirīvu?) is the Director of the Sacreds division of Wing Bind. Milieve is a very reserved woman, having remained quiet for the duration of the Top of Horns meeting on the Dark Dragon attack in Reverse London.

Cinderella (シンデレラ, Shinderera?) is one of the seven Märchens of Reverse London. She was found and formerly adopted as a pet by Macy Baljure, who had nicknamed her Elly. In her pre-molted form, Cinderella is closely connected to Macy Baljure's thoughts and emotions, allowing her to sense Macy's feelings and react to situations on her behalf. She becomes upset when Macy is mistreated or separated from her. Cinderella is generally obedient to Macy and follows her wishes. She also prefers eating fruits and vegetables. However, in her fully grown and molted form, Cinderella becomes highly destructive and unpredictable. Her Star Ash can cause widespread damage, often seemingly without intention. She no longer responds to Macy's attempts to communicate with her and may even act aggressively toward her. According to Ninny Spangcole, communication with Cinderella becomes nearly impossible in this form. As one of the Märchen, Cinderella is rumored to have existed before the formation of Reverse London and is believed to be an ancestor of Dark Dragons. Two months earlier, Macy discovered Cinderella as a small creature resting on a rock in the rain. At first, Macy thought she was imagining things, but soon realized Cinderella was real. She brought her home and discovered her preference for fruits and vegetables. Cinderella continued growing and gradually began resembling a Dragon. Since Macy was the only person who could see her, she developed a special bond with the creature and named her "Elly", believing that Cinderella would one day take her somewhere extraordinary.

Chiyo (千代, Chiyo) is a maid of the Kuchiki Clan and the personal servant of Rukia Kuchiki. Chiyo is a dutiful girl with a somewhat mischievous side, as she tends to laugh at inappropriate times.

Candice Catnipp (キャンディス・キャットニップ, Kyandisu Kyattonippu) is a Quincy and a member of the Wandenreich's Sternritter with the designation T: The Thunderbolt. Candice has a very short temper, as shown when she got annoyed at Bambietta for her habit of killing attractive male soldiers when irritated and then proceeded to get angry at Giselle for teasing her about her supposed tendency of having "fun" with her subordinates. She cares a great deal for her appearance, going as far as to get up hours before everyone else to do her hair, and cannot stand having it ruined in battle. Candice is also very shortsighted, reckless, and impatient; this volatile nature coupled with her horrible judgement of the situation causes her to make foolhardy decisions when engaging stronger opponents.

Bonnie (ボニー, Bonī), affectionately referred to as Bonnie-chan (ボニーちゃん, Bonī-chan), is a pet boar owned by Ganju Shiba. Bonnie was found by Ganju's brother Kaien in a mountainous area of Rukongai, when she was a piglet. She was injured at the time and was looked after by Kaien. Bonnie's ribbon was given to her by Kaien. Bonnie was very fond of Kaien and she is still not as emotionally attached to Ganju as she was to his brother.

Bambietta Basterbine (バンビエッタ・バスターバイン, Banbietta Basutābain) is a Quincy and a member of the Wandenreich's Sternritter with the designation E: The Explode. She is also the self-appointed leader of the Sternritter's female members. Bambietta is a particularly sadistic individual, evident in how she screams in joy as she slaughters her enemies. She is not above attacking her male subordinates to vent her frustration, sometimes bringing them into her room for "special relief" before killing them without remorse. She does not believe in fighting if one has already thrown away one's life. Bambietta refers to herself as the self proclaimed "leader" between her and some of her fellow Sternritter, and dislikes being abandoned by them and finds it quite embarrassing. In such cases she detonates the nearby environment in a destructive manner and implies she will reduce the area to flat land to bring them out. Bambietta has a strong sense of survival and self-preservation; during her second fight against Sajin Komamura, Bambietta was unable to understand the reasons for the lengths he went through in order to increase his power to kill Yhwach by offering his heart, with her stating her belief that the point of fighting is people not wanting to die and thus finding it incomprehensible for someone to throw away their life just to win a battle. Later after being severely injured by Komamura, Bambietta fell into panic due to knowing full well the repercussion of being defeated for a Sternritter and stating that she refuses to let it end like this. When about to be killed by Giselle to "save" her, Bambietta begged Giselle not to kill her, further highlighting her deep desire to survive. Later, upon being turned into a zombie by Giselle Gewelle, Bambietta's personality and behavior changes considerably. Though she retains her personality and a measure of free will, Bambietta has now become completely servile to Giselle and follows her orders without question.

Nana Baba (馬場奈奈, Baba Nana) is a student at Karakura High School and a classmate of Ichigo Kurosaki. Nana is present in her homeroom while Ichigo Kurosaki explains the reason behind his high grades. Two days later, she and her classmates are slightly unnerved and confused when Uryū Ishida arrives with heavily bandaged arms and claims to have fallen down the stairs.

Mizuho Asano (浅野 みづ穂, Asano Mizuho) is the older sister of Keigo Asano. She is the 24th Student Council President at Karakura 1st High School and handles multiple school affairs, including the local Kendo Club. Mizuho is very violent and gets angry over very small things, such as scolding her brother when it takes him some time to get juice or playing video games in her room. She is extremely fond of men with shaved heads, going so far as to allow Ikkaku Madarame to stay with her and Keigo due to his shaved head, despite not knowing him nor Yumichika Ayasegawa. She has an odd sense in fashion, dressing Ikkaku in a polka dot shirt with a heart and bear on the front, which Yumichika described it as unbelievable.

Tatsuki Arisawa (有沢 竜貴, Arisawa Tatsuki) is a student at Karakura High School, and is in the same class as Ichigo Kurosaki, her childhood friend and former karate partner. Tatsuki is a tomboy who is bold, outgoing, and extroverted. She is laid back and levelheaded most of the time, unless she is provoked by somebody. She aggressively uses her great strength to deal with anyone who troubles her or her friends. She easily hits anyone who annoys Orihime or gives her some sort of deep personal insult, seen when Kon, while inside Ichigo's body, gives her a compliment and apparently kisses her on the cheek. She stays angry for some time, even after wrecking much of the classroom and Kon flees the scene. She has a lot of insight on Ichigo's personality. When they were children, Tatsuki regularly saved Ichigo when he was getting beaten up, as well as cheering him up when he was upset. A tomboyish karate practitioner with dreams of becoming a vale tudo champion and already ranking Japan's second strongest in her age group, her only obvious feminine trait is how she writes her name using hiragana (たつき), though this is because she thinks it looks feminine while she considers the kanji of her name to be unappealing. Tatsuki is constantly protecting Orihime from men looking for a date, as well as the school lesbian Chizuru Honshō (who often approaches and tries to grab Orihime's chest). Tatsuki has done this since middle school, when she beat up some bullies who were trying to cut Orihime's hair, and had already done so once before Orihime's brother died. After that, Tatsuki promised to protect her from anyone who dared to make her cry, and she and Orihime became best friends.

Emilou Apacci (エミルー・アパッチ, Emirū Apacchi) is the 54th Arrancar in Sousuke Aizen's army and one of Tier Harribel's three Fracción, collectively known as the Tres Bestias. Apacci is impatient, short-tempered, rude, impulsive, and confrontational, and is usually scolded by Cyan Sung-Sun as a result. She is fiercely loyal to Harribel, finding the action of Hitsugaya raising his sword at her deeply offensive. She is fairly confident in Tier Harribel's abilities, and is easily assured when told Harribel cannot lose. Despite her irrational behavior Apacci has enough common sense to recognize who she sees as enemies. Despite being enemies with the Shinigami in the past, she warned Substitute Shinigami Ichigo Kurosaki not to get caught in the crossfires with Ayon, knowing her current enemies were the Wandenreich.